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Syntheses and electronic behaviors of net-worked,alternating hafnium-organic moiety hybrid copolymers
Authors:Hideo Matsui  Akira Okada  Taketoshi Kuroda  Yasuhiro Seguchi  Tetsuro Kawahara  Masakuni Yoshihara
Affiliation:(1) Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1, Kowakae, Higashiosaka Osaka, 577-8562, Japan;(2) Nippon Sheet Glass Co. Ltd., 1-7-2, Kaigan, Minatoku Tokyo, 105-8552, Japan;(3) Molecular Engineering Institute, Kinki University, 3-4-1, Kowakae, Higashiosaka Osaka, 577-8502, Japan
Abstract:Hafnium-organic moiety hybrid copolymers were prepared by reacting hafnium n-butoxide with organic diols. ESR spectral examinations of copolymers and ab-initio calculations of copolymer models suggest that an electron transfer from organic group to hafnium atom takes place.
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