超声波相转移催化合成β-萘乙醚 |
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引用本文: | 乔庆东,于大勇.超声波相转移催化合成β-萘乙醚[J].精细化工,1997,14(6):32-34. |
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作者姓名: | 乔庆东 于大勇 |
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作者单位: | 抚顺石油学院应用化学系 |
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摘 要: | 采用超声波作用下的相转移催化技术合成了香原料β 萘乙醚。经正交实验确定了最佳条件为:β 萘酚∶溴乙烷∶四丁基溴化铵=14∶10∶003(摩尔比),反应温度75℃,反应时间5h。产品纯度998%,产率可达942%,比传统的硫酸催化法(60%)和常规的相转移催化法(846%)的产率都高。
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关 键 词: | β-萘乙醚,相转移催化,超声波辐射 |
Synthesis of β Naphthal Ether by Ultrasonic Phase Transfer Catalysis |
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Abstract: | A perfume material,β naphthal ether,was synthesized by means of ultrasonic phase transfer catalysis(PTC) method.The optimum reaction conditions that were obtained by using orthogonal experiment were shown as follows:the ratio of β naphthal ether to ethane bromide to tetra butyl ammonium bromide was 1.4∶1.0∶0.03,the reaction temperature was 70~75℃ and the reaction time continued for 5 hours.The optimum production yield could be 94.2% which was higher than that of traditional sulfuric acid catalysis (60%)and ordinary PTC method (84.6%),and the purity determined by gas chromatography was 99.8%. |
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Keywords: | β naphthal ether phase transfer catalysis ultrasonic radiation |
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