Temperature stable high-Q microwave dielectric ceramics in (1 − x)BaTi4O9-xBaZn2Ti4O11 system

The microwave dielectric properties of (1 − x)BaTi₄O₉-xBaZn₂Ti₄O₁₁ ceramics were investigated by solid-state reaction technique for obtaining high-Q dielectric ceramics in BaO-ZnO-TiO₂ system. And they were strongly determined by the chemical composition. As x was increased from 0.05 to 0.50, BaZn₂Ti₄O₁₁ phase formed more and more. Therefore, the ε_r decreased from 37.3 to 32.8 and the Q × f values first raised from 45,300 GHz to 60,600 GHz (x = 0.30) and then started to decline to 58,700 GHz (x = 0.40), and the τ_f values varied gradually from 12 ppm/°C to − 13 ppm/°C. 0.7BaTi₄O₉-0.3BaZn₂Ti₄O₁₁ ceramics sintered at 1240 °C for 3 h had excellent comprehensive microwave dielectric properties: ε_r = 34.2, Q × f = 60,600 GHz and τ_f = − 2 ppm/°C.