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稠油低温氧化降粘剂的合成与性能评价
引用本文:刘德新,陈连涛,丁军涛,曹朋云.稠油低温氧化降粘剂的合成与性能评价[J].石油天然气学报,2008,30(3).
作者姓名:刘德新  陈连涛  丁军涛  曹朋云
作者单位:1. 中国石油大学石油工程学院,山东,东营,257061
2. 胜利油田井下作业公司,山东,东营,257077
3. 辽河油田分公司高升采油厂,辽宁,盘锦,124125
4. 盘锦中油辽河沥青有限公司,辽宁,盘锦,124125
摘    要:针对稠油低温氧化降粘技术,探讨了ⅤA族金属氧化物的有机化合物(Bi2O3)(acac)2](LTO-CB)催化氧化稠油的性能。研究了LTO-CB对稠油的降粘率随反应时间、浓度及温度的变化规律。结果表明,LTO-CB对稠油的低温氧化降粘作用与LTO-CB浓度、氢质子供体以及反应时间有关。LTO-CB在低温条件下通过降解沥青质来有效降低稠油粘度,对不同粘度的稠油降粘率可达50%以上。

关 键 词:稠油  低温氧化  催化氧化降解  降粘  降粘剂

Synthesis and its Performance Evaluation on Low-temperature Oxidization Viscosity Reducer for Heavy Oils
LIU De-xin,CHEN Lian-tao,DING Jun-tao,CAO Peng-yun.Synthesis and its Performance Evaluation on Low-temperature Oxidization Viscosity Reducer for Heavy Oils[J].Journal of Oil and Gas Technology,2008,30(3).
Authors:LIU De-xin  CHEN Lian-tao  DING Jun-tao  CAO Peng-yun
Abstract:The catalyzed oxidative performance of(Bi2O3)(acac)2(LTO-CB)for Heavy oil was investigated according to the technology of low-temperature oxidization viscosity-reducing.(Bi2O3)(acac)2 was an organic compound synthesised with the metal oxide of IIA and acac.Parameters,including reaction time,catalyst concentration and temperature that affected the change in viscosity-reducing were as well investigated.The experimental results show that the effect of viscosity-reducing for Heavy oil with LTO-CB is related with concentration,hydrogen proton donor and reaction duration.At low-temperature condition LTO-CB can effectively reduce the viscosity by oxidative degradation of asphaltenes in heavy oil,and the rate of viscosity-reducing reaches 50 percent for heavy oils with different viscosities.
Keywords:heavy oil  low-temperature oxidization  catalyzed oxidative degradation  viscosity-reducing  viscosity reducer
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