| 一种新型含咔唑基的ICT化合物的合成及光谱研究 |
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| 引用本文： | 郭晓东,高首勤,林培华,韩玉英,李俊芬,李笃信,董川,双少敏.一种新型含咔唑基的ICT化合物的合成及光谱研究[J].应用化工,2011,40(11):1901-1904. |
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| 作者姓名： | 郭晓东 高首勤 林培华 韩玉英 李俊芬 李笃信 董川 双少敏 |
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| 作者单位： | 1. 山西大学化学化工学院,山西太原,030006
2. 山西大学环境与工程研究中心,山西太原,030006 |
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| 基金项目： | 国家自然科学基金，山西省自然科学基金 |
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| 摘 要： | 以芴、咔唑为起始原料,经硝化、还原、烷基化、酰化、缩合六步反应,合成了一种新型ICT化合物9-乙基-3-咔唑亚甲基-芴腙(简称ECzFH)。产物及中间体的结构经IR、1H NMR等测试得到证实,并对其荧光性质进行了初步研究。结果表明,该化合物具有优良的电荷转移效果,且在二甲基亚砜溶剂中发出浅蓝色的荧光(Exmax=295 nm,Emmax1=358 nm,Emmax2=370 nm)。该化合物有望在生物分子探测、光电子集成、光动力学、医学诊断和双光子上转换激射等领域得到应用。
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| 关 键 词： | 咔唑衍生物 芴衍生物 腙 分子内电荷转移 合成 |
Synthesis and spectral study of a novel ICT compound containing carbazolyl |
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| GUO Xiao-dong,GAO Shou-qin,LIN Pei-hua,HAN Yu-ying,LI Jun-fen,LI Du-xin,DONG Chuan,SHUANG Shao-min.Synthesis and spectral study of a novel ICT compound containing carbazolyl[J].Applied chemical industry,2011,40(11):1901-1904. |
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| Authors: | GUO Xiao-dong GAO Shou-qin LIN Pei-hua HAN Yu-ying LI Jun-fen LI Du-xin DONG Chuan SHUANG Shao-min |
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| Affiliation: | GUO Xiao-dong1,GAO Shou-qin1,LIN Pei-hua1,HAN Yu-ying1,LI Jun-fen1,LI Du-xin1,DONG Chuan2,SHUANG Shao-min1(1.School of Chemistry and Chemical Engineering,Shanxi University,Taiyuan 030006,China,2.Research Center of Environmental Science and Engineering,China) |
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| Abstract: | A novel intramolecular charge transfer compound was synthesized from carbazole and fluorene by the nitration,reduction,alkylation,acylation,condensation reactions.The structure of products and intermediates were confirmed by IR and 1H NMR.Its fluorescence properties were researched preliminarily.The results showed that this compound had excellent effects of charge-transfer and emited the light blue flourescence in the DMSO(Exmax=295 nm,Emmax1=358 nm,Emmax2=370 nm).This compound was expected to a potential a... |
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| Keywords: | carbazole derivatives fluorene derivatives hydrazone intramolecular charge transfer(ICT) synthesis |
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