Optical properties of silicon-doped (100) GaAs layers grown by molecular-beam epitaxy

The photoluminescence spectra of (100) GaAs layers, both undoped and doped with silicon, is investigated at T=77 K. It is found that along with the B-band, which corresponds to interband radiative recombination, the spectra of doped layers also exhibit a so-called Si-band located near hν⋍1.4 eV. In multilayer δ-doped structures, an additional band appears in the region hν⋍1.47–1.48 eV, which is called here the δ-band. The dependence of the energy positions, intensities, and shapes of these photoluminescence bands on the doping dose N _Si, laser excitation power, and temperature are investigated. It is shown that the Si-band is caused by optical transitions between the conduction band and a deep acceptor level (∼100 meV) connected with Si atoms on As sites. It is also established that the dependences of the shape and intensity of the δ-band on temperature and photoluminescence excitation power are identical to the corresponding dependences for the B-band. The behavior of the δ-band in the photoluminescence spectra is viewed as evidence of quantum-well effects in the δ-doped structures. Fiz. Tekh. Poluprovodn. 32, 1060–1063 (September 1998)