Polycatenated Bilayer Structure Containing Honeycomb-like 63 Layers |
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| Authors: | Duan-Chuan Hou Gui-Yuan Jiang Fei Wang |
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| Affiliation: | 1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing, 102249, People’s Republic of China
3. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, People’s Republic of China
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| Abstract: | A new luminescent Zn(II) compound, [Zn2(IN)3(bpy)0.5(CH3COO)]·2(DMA) (1, IN = isonicotinate, bpy = 4,4′-bipyridine, DMA = N,N-dimethylacetamide), was synthesized under solvothermal condition and structurally characterized by single crystal X-ray diffraction. Compound 1 features a (3,4)-connected bilayer structure with honeycomb-like 63 layers and bpy pillars. Each individual bilayer is catenated with two adjacent bilayers, giving rise to a rare 2D + 2D → 3D polycatenation motif. |
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