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CFB-FGD 工艺中Ca(OH)2颗粒悬浮液最大分散度的实验研究
引用本文:王世昌,姚强,徐旭常. CFB-FGD 工艺中Ca(OH)2颗粒悬浮液最大分散度的实验研究[J]. 燃烧科学与技术, 2005, 11(3): 248-252
作者姓名:王世昌  姚强  徐旭常
作者单位:1. 清华大学热能工程系热能动力工程与热科学重点实验室,北京,100084;华北电力大学动力工程系,北京,102206
2. 清华大学热能工程系热能动力工程与热科学重点实验室,北京,100084
基金项目:国家重点基础研究发展规划(973)资助项目(G19990222).
摘    要:CFB-FGD工艺中的CaO颗粒粒径偏大,CaO转化率比较低.降低CaO颗粒粒径的途径之一是优化脱硫剂制备工艺.为此,研究了用5种不同制备工艺得到的Ca(OH)2颗粒悬浮液和悬浮液中Ca(OH)2颗粒的算术平均粒径.实验结果表明,采用0.006mol/L的六偏磷酸钠溶液与CaO水合反应得到的Ca(OH)2颗粒悬浮液的分散度增加了6.62倍,Ca(OH)2颗粒的算术平均粒径降低到了1053nm.这是一种简单、有效、经济的脱硫剂制备工艺.

关 键 词:循环流化床烟气脱硫工艺 Ca(OH)2颗粒 悬浮液 分散度
文章编号:1006-8740(2005)03-0248-05
修稿时间:2004-11-08

Experimental Study on the Maximum Dispersion Rate of the Ca (OH) 2 Particles-Water Suspension Liquid for CFB-FGD Process
WANG Shi-chang,YAO qiang,XU Xu-chang. Experimental Study on the Maximum Dispersion Rate of the Ca (OH) 2 Particles-Water Suspension Liquid for CFB-FGD Process[J]. Journal of Combustion Science and Technology, 2005, 11(3): 248-252
Authors:WANG Shi-chang  YAO qiang  XU Xu-chang
Affiliation:WANG Shi-chang~
Abstract:The CaO particle diameter in CFB(circulating fluidized bed)-FGD(flue gas desulphurization) technology is so large that the conversion rate of CaO in de-sulfurization reaction is rather low. To reduce the CaO particle diameter, the preparation process of absorbent must be optimized. This paper studied 5 different kinds of Ca(OH)_2 particle suspension liquid and the Ca(OH)_2 particle diameter. The experimental results reveale that hydration of solution of (NaPO_3)_6 with the concentration of 0.006 mol/L and CaO particles increase the dispersion rate by 6.62 times and the Ca(OH)_2 particle diameter is reduced to 1 053 nm. This is a simple, effective and economical process for the absorbents preparation of CFB-FGD technology.
Keywords:CFB-FGD process  Ca(OH)_2 particles  suspension liguid  dispersion rate
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