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Dimerization of 1-isopropenyl anthracene by TiCl4
Authors:Jean Coudane  Maryvonne Brigodiot  Ernest Marechal
Affiliation:(1) Laboratoire de Chimie Macromoléculaire, Institut National Superieur de Chimie Industrielle de Rouen, B.P. 08, 76130 Mont Saint Aignan, France;(2) Laboratoire de Synthèse Macromoléculaire, Université Pierre et Marie Curie, Tour 44, 1er étage, 4, Place Jussieu, 75230 Paris Cedex 05, France
Abstract:Summary 1-isopropenyl anthracene was dimerized by reaction with TiCl4 in CH2Cl2 and the structure of the dimer studied by 1H NMR spectroscopy. The spectrum was assigned and is in agreement with simulation. The structure results from the attack of carbocation on carbon 9.
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