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TPU/POE共混体系的热解动力学研究
引用本文:李冲,魏永春,何晓红,廖正福,陈旭东.TPU/POE共混体系的热解动力学研究[J].广西化工,2012(7):19-24.
作者姓名:李冲  魏永春  何晓红  廖正福  陈旭东
作者单位:[1]北京理工大学珠海学院,广东珠海519085 [2]广东工业大学材料与能源学院,广东广州510090 [3]中山大学化学工程学院,广东广州510275
摘    要:通过热重分析仪研究了TPU/POE的热解动力学,并用多升温速率法中的Kissinger和Ozawa(F-W-O)2种方法计算样品的E,发现除样品POE-MA外,2种方法的结果比较吻合。另外采用单升温速率法研究TPU的热解动力学,并与多升温速率法比较,发现2种方法的结果同样一致。

关 键 词:TPU/POE共混物  共混体系  热重分析仪  热解动力学

Study on Pyrolysis Reaction Dynamics of TPU/POE Blending System
LI Chong,WEI Yong-chun,HE Xiao-hong,LIAO Zheng-fu,CHEN Xu-dong.Study on Pyrolysis Reaction Dynamics of TPU/POE Blending System[J].Guangxi Chemical Industry,2012(7):19-24.
Authors:LI Chong  WEI Yong-chun  HE Xiao-hong  LIAO Zheng-fu  CHEN Xu-dong
Affiliation:1.College of Chemical & Material,Zhuhai Campus of Beijing Institute of Technology,Zhuhai 519085,China;2.College of Materials and Energy,Guangdong University of Technology,Guangzhou 510090,China;3.School of Chemistry and Chemical Engineering,Zhongshan University,Guangzhou 510275,China)
Abstract:The pyrolysis reaction dynamics for a new thermoplastic polyurethane/poly(ethylene-octene)(TPU/POE) blending system was studied by thermogravimetry analyzer(TG).The results showed that the except for the POE-MA,the methods of Kissinger and Ozawa(F-W-O) for E in the multi-heating rate method were compared.Besides,the pyrolysis reaction dynamics of TPU was studied by the single heating rate method,the multi-heating rate method was compared and the result were consistent.
Keywords:thermoplastic polyurethane/poly(ethylene-octene) copolymer blend  blending system  thermogravimetry analyzer  pyrolysis reaction dynamics  
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