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Cu_2ZnSnS_4薄膜的研究进展
引用本文:蔡倩,梁晓娟,向卫东,钟家松,邵明国,赵肖为.Cu_2ZnSnS_4薄膜的研究进展[J].材料导报,2012,26(3):138-143.
作者姓名:蔡倩  梁晓娟  向卫东  钟家松  邵明国  赵肖为
作者单位:1. 温州大学化学与材料学院,温州,325035
2. 温州大学化学与材料学院,温州325035;同济大学材料科学与工程学院,上海200092
3. 同济大学材料科学与工程学院,上海,200092
基金项目:国家自然科学基金,浙江省重点科技创新团队
摘    要:Cu2ZnSnS4(CZTS)薄膜太阳能电池具有低成本、高效率、安全无毒等优点,是最具发展前景的太阳能电池之一,近几年来开始受到广泛关注。简要介绍了国内外几种制备Cu2ZnSnS4薄膜的方法,包括蒸发法、溅射法、脉冲激光沉积法、电化学沉积法、喷涂热解法、Sol-gel法、丝网印刷法,并阐述了这几种方法的优点及存在的问题,展望了今后CZTS薄膜的研究方向,认为通过溶剂热或热注入法制备出CZTS纳米晶体后,再通过丝网印刷法或旋涂等法制成CZTS薄膜能降低生产成本,在电池的工业化生产中具有很广阔的应用前景。

关 键 词:CuZnSnS  太阳能电池  薄膜

The Development of Cu2ZnSnS4 Thin Films
CAI Qian , LIANG Xiaojuan , XIANG Weidong , ZHONG Jiasong , SHAO Mingguo , ZHAO Xiaowei.The Development of Cu2ZnSnS4 Thin Films[J].Materials Review,2012,26(3):138-143.
Authors:CAI Qian  LIANG Xiaojuan  XIANG Weidong  ZHONG Jiasong  SHAO Mingguo  ZHAO Xiaowei
Affiliation:1(1 College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035;2 College of Materials Science and Engineering,Tongji University,Shanghai 200092)
Abstract:Cu2ZnSnS4(CZTS) thin film solar cells proved to be one of the most fascinating materials in solar cell fields owning to its low cost,high absorption coefficient,security and non-toxic and so on.Several methods to prepare Cu2ZnSnS4 thin films includes are briefly introduced,the processes includes thermal evaporation,sputtering,pulsed laser deposition,electrochemical deposition,spray pyrolysis,sol-gel,screen printing methods,their advantages and existing problems are stated.Finally,the future researches and development of prospects of Cu2ZnSnS4 thin films are also estimated.The nanocrystals which synthesized through solvothermal or hot-injection can used for preparing CZTS thin films by screen printing or coating method,this route will help decrease the cost of production and suitable for extensive industrialization produce.
Keywords:Cu2ZnSnS4  solar cells  thin film
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