| 室温反应合成ZnSe粉体工艺研究 |
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| 引用本文： | 刘长友,孙晓燕,王涛,查钢强,介万奇. 室温反应合成ZnSe粉体工艺研究[J]. 材料导报, 2012, 26(2): 10-13 |
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| 作者姓名： | 刘长友 孙晓燕 王涛 查钢强 介万奇 |
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| 作者单位： | 西北工业大学材料学院凝固技术国家重点实验室,西安,710072 |
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| 基金项目： | 国家科技部973计划，凝固技术国家重点实验室自主课题，西北工业大学基础研究基金 |
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| 摘 要： | 室内自然环境下在三乙醇胺(Triethanolamine,TEA)中利用硼氢化钾(KBH4)固相还原单质硒(Se),获得了稳定的硒氢酸根离子(HSe-)。在TEA中通过HSe-与ZnSO4.7H2O反应制备了橙黄色中间体。有机元素分析、全谱直读等离子体发射光谱(ICP)分析、红外光谱和紫外-可见光谱等测试结果表明,中间体由无机化合物组成。采用中间体分解、碱中和和二次还原工艺分别获得了初级、纯化和单相的ZnSe粉体。XRD和HRTEM测试结果表明,所制ZnSe粉体具有闪锌矿结构。室温荧光光谱测试结果显示样品在470nm和500nm具有强的荧光发射。
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| 关 键 词： | 硒化锌 室温反应 固相还原 |
Process for Reaction Synthesis of ZnSe Powders at Room Temperature |
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| LIU Changyou , SUN Xiaoyan , WANG Tao , ZHA Gangqiang , JIE Wanqi. Process for Reaction Synthesis of ZnSe Powders at Room Temperature[J]. Materials Review, 2012, 26(2): 10-13 |
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| Authors: | LIU Changyou SUN Xiaoyan WANG Tao ZHA Gangqiang JIE Wanqi |
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| Affiliation: | (State Key Laboratory of Solidification Processing,School of Materials Science and Engineering,Northwestern Polytechnical University,Xi’an 710072) |
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| Abstract: | The air-stable HSe-ion was prepared by solid-state reducing element Se using KBH4 in triethanolamine(TEA) at ambient temperature.The orange precursor or intermediate was obtained by the reaction between HSe-ion and ZnSO4·7H2O in TEA.The results of organic elemental analysis,ICP analysis,IR and UV-Vis spectra indicate that the intermediate is consist of inorganic compounds.The primary,refined and pure ZnSe powders were synthesized by ambient decomposition of intermediate,neutralization reaction and re-reduction,respectively.The XRD and HRTEM results show that the as-synthesized ZnSe powders are cubic zinc blende structure.Room temperature PL spectrum of as-synthesized sample shows strong emissions at wavelengths of 470nm and 500nm. |
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| Keywords: | zinc selenide room-temperature reaction solid state reduction |
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