| 金属镁在有机反应中的应用 |
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| 引用本文： | 陈仕艳,李方正,林吉茂.金属镁在有机反应中的应用[J].化学试剂,2000,22(3):153-156. |
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| 作者姓名： | 陈仕艳 李方正 林吉茂 |
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| 作者单位： | 山东大学化学院,济南,250100 |
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| 摘 要： | 综述了近２０年来金属镁在有机反应中的应用。它可用于加氢还原、砜脱硫酰基、亚砜脱氧、产生二卤卡宾、制备混合醚、二元醇消除、席夫碱的烯丙基化、膦酸酯或亚膦酸酯的Ｃ－Ｏ键断裂、有机硅的Ｓｉ－Ｏ－Ｓｉ键断裂等反应中。
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| 关 键 词： | 镁 有机反应 应用 加氢还原反应 亚砜脱氧反应 |
| 文章编号： | 0258-3283(2000)03-0153-04 |
| 修稿时间： | 1998-12-08 |
Application of magnesium in organic reactions |
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| Chen Shiyan,Li Fangzheng,Lin Jimao.Application of magnesium in organic reactions[J].Chemical Reagents,2000,22(3):153-156. |
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| Authors: | Chen Shiyan Li Fangzheng Lin Jimao |
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| Affiliation: | Chen Shiyan
,Li Fangzheng
,Lin Jimao
(Department of Chemistry, Shandong University, Jinan 250100) |
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| Abstract: | This paper reviews the applications of magnesium in organic reactions in the last twenty years. Magnesium can be used in many reactions, such as hydrogenation reduction. desulfonation of alkyl phenyl sulfones, deoxygenation of alkyl or alkenyl phenyl sulfoxides, preparation of dichlorocarbene, preparation of mixed ethers, elimination of diols, allylation of imines, O-dealkylation of phosphoric and phosphonic acid esters, as well as Si-O-Si bond breaking of organosilicons. |
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| Keywords: | magnesium organic reaction application |
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