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Applications of Free Radicals in Organic Synthesis
Authors:Dale L. Boger
Affiliation:Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA
Abstract:A summary of studies on the generation of acyl radicals and their subsequent use in intermolecular, intramolecular, macrocyclization, and tandem alkene addition reactions is provided. Similarly, the use of intramolecular free radical cyclization reactions in the total synthesis of (+)-CC-1065 and a series of structurally related analogs is summarized.
Keywords:
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