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柔性环氧灌浆材料的制备与性能研究
引用本文:王永珍,张亚峰,邝健政,雷翅,徐宇亮. 柔性环氧灌浆材料的制备与性能研究[J]. 化工新型材料, 2011, 39(9): 88-91
作者姓名:王永珍  张亚峰  邝健政  雷翅  徐宇亮
作者单位:1. 中科院广州化学研究所,广州510650;中科院研究生院,北京100049
2. 中科院广州化学研究所,广州510650;中科院广州化灌工程有限公司,广州510070;广东省化学灌浆工程技术研究开发中心,广州510650
3. 中科院广州化灌工程有限公司,广州510070;广东省化学灌浆工程技术研究开发中心,广州510650
摘    要:采用十八胺与乙二醇缩水甘油醚为原料,制得一种两端为环氧基、中间氮原子上接有长疏水侧链的加成物,再由自制亚胺上剩余的仲胺对加成物进行封端,制备出潜伏型柔性环氧固化剂.并用该固化剂制备出低模量高弹性环氧灌浆材料.通过测定固化物的冲击强度、拉伸强度、断裂伸长率和玻璃化转变温度(Tg),扫描电子显微镜对固化物的断裂面形态分析等...

关 键 词:柔性  冲击强度  断裂伸长率  弯曲性能  环氧灌浆材料

Preparation and properties of flexible epoxy grouting material
Wang Yongzhen,Zhang Yafeng,Kuang Jianzheng,Lei Chi,Xu Yuliang. Preparation and properties of flexible epoxy grouting material[J]. New Chemical Materials, 2011, 39(9): 88-91
Authors:Wang Yongzhen  Zhang Yafeng  Kuang Jianzheng  Lei Chi  Xu Yuliang
Affiliation:Wang Yongzhen1,4 Zhang Yafeng1,2,3 Kuang Jianzheng1,3 Lei Chi1,4 Xu Yuliang2,3(1.Guangzhou Institute of Chemistry,CAS,Guangzhou 510650,2.Guangzhou Chemical grouting engineering Co.LTD.,Guangzhou 510070,3.Guangdong Prov.E.R.C.for Chemical Grouting,4.Graduate School of Chinese Academy of Sciences,Beijing 100049)
Abstract:A latent and flexible epoxy curing agent was synthesized by the reaction of synthetic epoxy compound and ketimine which was synthesized by diethylenetriamine and methyl isobutyl ketone.And the synthetic epoxy compound having a long hydrophobic alkyl side chain on the N atom and terminated by epoxy groups was synthesized from octadecanamine and the ethylene glycol diglycidyl ether.And a type of flexible epoxy grouting material was prepared based on the curing agent.By means of checking the impact strength,te...
Keywords:flexibility  impact strength  elongation at break  flexural property  epoxy grouting material  
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