| 金刚烷直接氧化制备金刚烷多元醇新工艺 |
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| 引用本文： | 付长安,郭建维,刘卅,崔英德,杨楚芬,彭进平,崔亦华. 金刚烷直接氧化制备金刚烷多元醇新工艺[J]. 化工学报, 2011, 62(12): 3428-3433. DOI: 10.3969/j.issn.0438-1157.2011.12.018 |
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| 作者姓名： | 付长安 郭建维 刘卅 崔英德 杨楚芬 彭进平 崔亦华 |
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| 作者单位： | 1.广东工业大学轻工化工学院，广东 广州 510006;2.华南理工大学材料科学与工程学院，广东 广州 510640 |
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| 基金项目： | 番禺科技计划项目(2009-z-40-1); 广东工业大学重大培育专项(405095220)~~ |
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| 摘 要： | 引言金刚烷(三环[3.3.1.1]3,7癸烷)是一种周正对称、高度稳定的笼状饱和烃,它的4个桥头碳上的氢具有较强的化学反应能力,可以被选择性地取代引入相同或不同的基团,这使得分子的可设计性
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| 关 键 词： | 金刚烷 氧化 金刚烷多元醇 |
A novel synthesis of adamantane polyhydric alcohols by direct oxidation of adamantane |
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| FU Chang' an,GUO Jianwei,LIU Sa,CUI Yingde,YANG Chufen,PENG Jinping,CUI Yihua. A novel synthesis of adamantane polyhydric alcohols by direct oxidation of adamantane[J]. Journal of Chemical Industry and Engineering(China), 2011, 62(12): 3428-3433. DOI: 10.3969/j.issn.0438-1157.2011.12.018 |
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| Authors: | FU Chang' an GUO Jianwei LIU Sa CUI Yingde YANG Chufen PENG Jinping CUI Yihua |
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| Affiliation: | FU Chang'an1,GUO Jianwei1,LIU Sa2,CUI Yingde1,YANG Chufen1,PENG Jinping1,CUI Yihua1(1Faculty of Chemical Engineering & Light Industry,Guangdong University of Technology,Guangzhou 510006,Guangdong,China,2School of Materials Science & Engineering,South China University of Technology,Guangzhou 510640,China) |
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| Abstract: | Adamantane polyhydric alcohols are important active intermediates for synthesis of adamantane-based specific medicines, fine chemicals and functional materials.In this paper, three adamantane polyhydric alcohols, including adamantane-1,3-diol, adamantane-1,3,5-triol and adamantane-1,3,5,7-tetraol were synthesized via one-step oxidation reaction of adamantane by using Cr(Ⅵ）reagents as oxidants, acetic acid as solvent under the mild conditions.The structures of adamantane-1,3-diol, adamantane-1,3,5-triol and adamantane-1,3,5,7-tetraol were confirmed by IR, 1H NMR and element analysis.Influences of synthesis conditions on the oxidation reaction were investigated.The reaction mechanism of adamantane oxidation by Cr(Ⅵ）reagents was discussed as well.Under the optimum conditions, adamantane-1,3-diol, adamantane-1,3,5-triol and adamantane-1,3,5,7-tetraol could be synthesized with the yields of 71%, 42% and 35% respectively.Such synthesis technology for adamantane polyhydric alcohols is of potential for application because of brief reaction, convenient manipulation, and the mild conditions and so on. |
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| Keywords: | adamantane oxidation adamantane polyhydric alcohols |
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