The influence of temperature on the current peak multiplicity related to the nickel hydroxide electrode |
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Authors: | H. Gómez Meier J. R. Vilche A. J. Arvia |
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Affiliation: | (1) División Electroquimica, Instituto de Investigations Fisicoquimicas Teóricas y Aplicadas, Sucursal 4, Casilla de Correo 16, 1900 La Plata, Argentina |
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Abstract: | The splitting of the anodic and cathodic potentiodynamic E/I display of the nickel hydroxide electrode in 1 N KOH between 0 and 75° C is reported. The formal first order rate constants for the chemical reactions which occur simultaneously with the electrochemical steps, and the corresponding activation energies are evaluated. The results are discussed on the basis of the reaction model recently proposed for the nickel hydroxide electrode. |
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