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Facile chromaticity approach for the inspection of passive films on austenitic stainless steel
Affiliation:1. Department of Chemistry, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran;2. Young Researchers and Elite Club, Science and Research Branch, Islamic Azad University, Tehran, Iran;3. Department of Biology, Central Tehran Branch, Islamic Azad University, Tehran, Iran;1. Department of Materials Science and Engineering, Pusan National University, Busan 46141, Republic of Korea;2. Global Core Research Center for Ships and Offshore Plants, Pusan National University, Busan 46141, Republic of Korea;3. Material Analysis Laboratory, DAE-IL Corporation, Ulsan 44911, Republic of Korea;4. Platform Technology Lab., Samsung Electronics Co., Ltd., Suwon 16678, Republic of Korea;1. Institute of Materials Science, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China;2. New Industry Creation Hatchery Center, Tohoku University, Sendai 980-8579, Japan;3. Shanghai Nuclear Engineering Research & Design Institute, Shanghai 200233, China;1. Department of Mechanical Engineering, TEMA, University of Aveiro, Campus Universitário de Santiago, 3810–193 Aveiro, Portugal;2. Faculty of Electrical Engineering, Mechanical Engineering and Naval Architecture, University of Split, R. Boškovića 32, HR-21000 Split, Croatia;3. Faculty of Mechanical Engineering, University of Maribor, Smetanova ul. 17, SI-2000 Maribor, Slovenia;1. Faculty of Nanotechnology and Advanced Materials Engineering, Sejong University, Seoul 143-747, South Korea;2. Department of Printed Electronics Engineering, Sunchon National University, Chonnam 540-742, South Korea
Abstract:A chromaticity approach for the inspection of passive films on 304 stainless steel is explored by measuring the redness degree of the colouration reaction product of phenanthroline. The measurement exhibits good capability in evaluating film quality. The measured values are dependent on the structural integrity of the passive films. Based on the electrochemical examination and XPS spectra, this approach is discussed from the view point of the inhibition of the passive films on the release of ferrous from the matrix during its reaction with phenanthroline. The preferential dissolution of Fe-rich oxides in the films can affect the measurement.
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