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Effects of LaB6 addition on arc-jet convectively heated SiC-containing ZrB2-based ultra-high temperature ceramics in high enthalpy supersonic airflows
Affiliation:1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Institute of Functional Materials, Donghua University, Shanghai 201620, China;2. School of Metallurgy and Materials, University of Birmingham, B15 2TT, UK;3. SZU-NUS Collaborative Innovation Center for Optoelectronic Science & Technology, International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China
Abstract:The performances of a ZrB2–SiC–LaB6 ultra-high temperature ceramic (UHTC) was investigated in high enthalpy supersonic air flow. The UHTC material reached and maintained steady-state radiative surface temperature of 1973 K (monitored by pyrometer) for 5 min, and survived the arc-jet plasma exposure without any optical evidence of mechanical damage. The oxide scale covering externally the sample evolved into different textures. Transient thermal analysis processed via CFD provided a good agreement between the numerical steady-state temperature and the temperature distribution obtained experimentally. The contemporary addition of LaB6 and SiC to ZrB2 had a detrimental effect on the overall oxidation resistance.
Keywords:A  Ceramic matrix composites  B  SEM  B  XRD  B  Modelling studies  C  Oxidation  C  Oxide coatings
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