Synergy effect in the photocatalytic degradation of methylene blue on a suspended mixture of TiO2 and N-containing carbons |
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Affiliation: | 1. Utsunomiya University, 7-1-2 Yoto, Utsunomiya 321-8585, Tochigi, Japan;2. National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047, Ibaraki, Japan |
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Abstract: | N-containing carbon materials were obtained from waste plum stones submitted to pyrolysis under Ar flow at 700 °C or to activation under steam at 800 °C and enriched with nitrogen by heating in a NH3/air mixture at 270 °C or in NO at 300 °C. In situ mixtures of TiO2 and carbons were prepared by the slurry method and methylene blue photodegradation was chosen as a model reaction to verify the influence of N-containing carbons on the photocatalytic activity of TiO2 under artificial visible light irradiation. From the kinetics of methylene blue degradation an important synergy effect between both solids was detected with a remarkable increase up to a factor of 5.3 higher in the photocatalytic activity on TiO2–C than that on TiO2 alone. A mechanism for the photoassisting role of N-containing carbons upon the photoactivity of TiO2 under visible light is discussed. |
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