Reduction of Sulfoxides to Sulfides in the Presence of Copper Catalysts |
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| Authors: | Stephan Enthaler Maik Weidauer |
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| Affiliation: | 1.Technische Universit?t Berlin, Department of Chemistry,Cluster of Excellence “Unifying Concepts in Catalysis”,Berlin,Germany |
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| Abstract: | Abstract Copper complexes catalyze the reduction of aliphatic and aromatic sulfoxides in the presence of silanes as reducing reagent.
The influence of different reaction parameters on the catalytic activity is investigated in detail. The scope and limitations
of the described catalyst is demonstrated in the reduction of various sulfoxides. In most cases, high conversion and excellent
chemoselectivity are obtained. |
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