| （4-苯硫基-苯基）二苯基硫鎓六氟磷酸盐的合成研究 |
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| 引用本文： | 贾丽慧 刘安昌 余磊. （4-苯硫基-苯基）二苯基硫鎓六氟磷酸盐的合成研究[J]. 感光科学与光化学, 2006, 24(4): 301-305 |
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| 作者姓名： | 贾丽慧 刘安昌 余磊 |
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| 作者单位： | 湖北省新型反应器与绿色化工重点实验室，湖北省新型反应器与绿色化工重点实验室，湖北省新型反应器与绿色化工重点实验室 武汉430074，武汉工程大学化工与制药学院，武汉430074，武汉430074，武汉工程大学化工与制药学院，武汉430074，武汉430074，武汉工程大学化工与制药学院，武汉430074 |
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| 摘 要： | 以P2O5为脱水剂,甲烷磺酸为溶剂,二苯亚砜与二苯硫醚反应制备了(4-苯硫基-苯基)二苯基硫六氟磷酸盐.对产物进行了元素分析、紫外光谱、红外光谱、气-质联用和核磁共振的结构确证.该硫盐对环氧树脂具有良好的固化性能.
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| 关 键 词： | 硫鎓盐 二苯硫醚 甲烷磺酸 |
| 文章编号： | 1000-3231（2006）04-0301-05 |
| 收稿时间： | 2006-01-06 |
| 修稿时间： | 2006-04-20 |
Synthesis of (4-Phenylthio)Phenyl Diphenyl Sulfonium Hexafluorophosphate Salt |
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| JIA Li-hui, LIU An-chang, YU Lei. Synthesis of (4-Phenylthio)Phenyl Diphenyl Sulfonium Hexafluorophosphate Salt[J]. Photographic Science and Photochemistry, 2006, 24(4): 301-305 |
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| Authors: | JIA Li-hui LIU An-chang YU Lei |
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| Affiliation: | 1. Hubei Provincial Key Laboratory of Novel Reactor and Green Chemical Technology, Wuhan 430074, Hubei , P. R. China ; 2. School of Chemical Engineering and Pharmacy, Wuhan Institute of Chemical Technology, Wuhan 430074, Hubei , P. R . China |
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| Abstract: | (4-phenylthio)phenyl diphenyl sulfonium hexafluorophosphate were prepared by the condensation of biphenyl sulfoxide with biphenyl sulfide,in the presence of P_2O_5 used as dehydration(agent) and methanesulfonic acid used as solvent.4-(phenylthio)triphenylsulfonium hexafluorophosphate was identified by elemental analysis,UV,IR,G-MC and H-NMR.The sulfonium salt has better curing character to epoxy resin. |
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| Keywords: | sulfonium salt biphenyl sulfide methanesulfonic acid |
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