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Upconversion Emission in Er^3+ Doped Novel Bismuthate Glass
引用本文:孙洪涛,戴世勋,徐时清,张丽艳,陈宝玉,胡丽丽.Upconversion Emission in Er^3+ Doped Novel Bismuthate Glass[J].中国稀土学报(英文版),2005,23(3):331-335.
作者姓名:孙洪涛  戴世勋  徐时清  张丽艳  陈宝玉  胡丽丽
作者单位:Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,China,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,China,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,China,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,China,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,China,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,China
基金项目:国家自然科学基金,上海市科委资助项目
摘    要:Novel Er3 -doped bismuth lead strontiam glass was fabricated and characterized, and the absorption spectrum and upconversion spectrum of the glass were studied. The Judd-Ofelt intensity parameters Ωt (t=2, 4, 6) were found to be Ω2=3.27×10-20 cm2, Ω4=1.15×10-20 cm2, and Ω6=0.38×10-20 cm2. The oscillator strength, the spontaneous transition probabilities, the fluorescence branching ratios, and excited state lifetimes were also measured and calculated. The upconversion emission intensity varies with the power of infrared excitation intensity. A plot of log Iup vs log IIR yields a straight line with slope 1.86, 1.88 and 1.85, corresponding to 525, 546, and 657 nm emission bands, respectively, which indicates that a two-photon process for the red and green emission.

关 键 词:无机非金属材料  玻璃  稀土  分光镜

Upconversion Emission in Er3+ Doped Novel Bismuthate Glass
Sun Hongtao,DAI Shixun,Xu Shiqing,Zhang Liyan,Chen Baoyu,Hu Lili.Upconversion Emission in Er3+ Doped Novel Bismuthate Glass[J].Journal of Rare Earths,2005,23(3):331-335.
Authors:Sun Hongtao  DAI Shixun  Xu Shiqing  Zhang Liyan  Chen Baoyu  Hu Lili
Abstract:
Keywords:inorganic nonmetallic materials  bismuth lead strontiam glass  Er3  ion  spectroscopic properties  Judd-Ofelt theory  rare earths
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