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催化部分氧化甲烷制合成气的平衡热力学研究
引用本文:徐健,魏伟胜,鲍晓军.催化部分氧化甲烷制合成气的平衡热力学研究[J].中国化学工程学报,2002,10(1):56-62.
作者姓名:徐健  魏伟胜  鲍晓军
作者单位:TheKeyLaboratoryofCatalysis,ChinaNationalPetroleumCo.,UniversityofPetroleum,Beijing102200,China
基金项目:the China National Petroleum Co. (CNPC).
摘    要:The catalytic partial oxidation of methane to syngas (CO H2) has been simulated thermodynamically with the advanced process simulator PRO/Ⅱ. The influences of temperature,pressure,CH4/O2 ratio and steam addition in feed gas on the conversion of CH4 selectively to syngas and heat duty required were investigated, and their effects on carbon formation were also discussed. The simulation results were in good agreement with the literature data taken from a spouted bed reactor.

关 键 词:热力学  部分氧化催化  甲烷  合成气
修稿时间: 

Thermodynamic Study on the Catalytic Partial Oxidation of Methane to Syngas
Xn Jian,WEI Weisheng,BAO Xiaojun.Thermodynamic Study on the Catalytic Partial Oxidation of Methane to Syngas[J].Chinese Journal of Chemical Engineering,2002,10(1):56-62.
Authors:Xn Jian  WEI Weisheng  BAO Xiaojun
Affiliation:The Key Laboratory of Catalysis, China National Petroleum Co., University of Petroleum, Beijing 102200, China
Abstract:The catalytic partial oxidation of methane to syngas (CO+H2) has been simulated thermodynamically with the advanced process simulator PRO/II. The influences of temperature, pressure, CH4/O2 ratio and steam addition in feed gas on the conversion of CH4 selectively to syngas and heat duty required were investigated, and their effects on carbon formation were also discussed. The simulation results were in good agreement with the literature data taken from a spouted bed reactor.
Keywords:methane  partial oxidation  syngas  thermodynamic simulation
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