| 甲烷水合物在纯水和抑制剂体系中的生成动力学 |
| |
| 引用本文： | 裘俊红,郭天民.甲烷水合物在纯水和抑制剂体系中的生成动力学[J].中国化学工程学报,2002,10(3):316-322. |
| |
| 作者姓名： | 裘俊红 郭天民 |
| |
| 作者单位： | [1]ResearchCenterofScience,ZhejiangUniversityofTechnology,Hangzhou310032,China [2]FluidPhaseBehavior＆PropertyResearchLaboratory,UniversityofPetroleum,Beijing100083,China |
| |
| 基金项目： | Supported by the National Natural Science Foundation(No. 20003010) and Postdoctoral Research Foundation. |
| |
| 摘 要： | Kinetic data of methane hydrate formation in the presence of pure water,brines with single salt and mixed salts,and aqueous solutions of ethylene glycol(EG) and salt EG were measured.A new kinetic model of hydrate formation for the methane water systems was developed based on a four-step formation mechanism and reaction kinetic approach.The proposed kinetic model predicts the kinetic behavior of methane hydrate formation in pure water with good accuracy.The feasibility of extending the kenetic model of salt(s) and EG containing systems was explored.
|
| 关 键 词： | 动力学 甲烷水合物形成 抑制剂 纯水 盐水 乙二醇 |
| 修稿时间： | |
Kinetics of Methane Hydrate Formation in Pure Water and Inhibitor Containing Systems |
| |
| QIU Junhong,GUO Tianmin.Kinetics of Methane Hydrate Formation in Pure Water and Inhibitor Containing Systems[J].Chinese Journal of Chemical Engineering,2002,10(3):316-322. |
| |
| Authors: | QIU Junhong GUO Tianmin |
| |
| Affiliation: | Fluid Phase Behavior & Property Research Laboratory, University of Petroleum, Beijing 100083, China |
| |
| Abstract: | Kinetic data of methane hydrate formation in the presence of pure water, brines with single salt and mixed salts, and aqueous solutions of ethylene glycol(EG) and salt+EG were measured. A new kinetic model of hydrate formation for the methane+water systems was developed based on a four-step formation mechanism and reaction kinetics approach. The proposed kinetic model predicts the kinetic behavior of methane hydrate formation in pure water with good accuracy. The feasibility of extending the kinetic model to salt(s) and EG containing systems was explored. |
| |
| Keywords: | kinetics hydrate formation inhibitors methane brine |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《中国化学工程学报》浏览原始摘要信息 |
|
点击此处可从《中国化学工程学报》下载全文 |
