Adsorption as a Method of Doping 3-mol%-Yttria-Stabilized Zirconia Powder with Copper Oxide |
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Authors: | John R Seidensticker Merrilea J Mayo K Osseo-Asare |
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Affiliation: | Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 |
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Abstract: | The adsorption behavior of Cu2+ on 3-mol%-yttria-stabilized tetragonal zirconia polycrystalline (3Y-TZP) powder was studied. There is a window of ph values (10 < pH < 11) where adsorption may be used as a method of doping 3Y-TZP with Cu2+. The maximum mole percent of the CuO additions is determined by the specific surface area of the 3Y-TZP powder; a powder with a specific surface area of 16.1 m2/g is limited to about 1 mol% CuO. Compacts made from powders doped with CuO using this method exhibited an enhancement in superplasticity comparable to that observed in other studies using samples doped with CuO by attrition milling. |
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