Organometallic Coordination Networks Based on \uppi-Bonded Transition Metal Quinonoid Complexes期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Organometallic Coordination Networks Based on \uppi-Bonded Transition Metal Quinonoid Complexes

Authors:	Jeffrey A Reingold Seung Uk Son Gene B Carpenter Dwight A Sweigart

Affiliation:	(1) Department of Chemistry, Brown University, Providence, RI 02912, USA;(2) Department of Chemistry, Sungkyunkwan University, Suwon, 440-746, Korea

Abstract:	Hydroquinones $\uppi$ -bonded to the transition metal fragments Mn(CO) , Rh(COD)⁺, and RhP(OPh)₃]₂⁺ are readily deprotonated to afford anionic $\upeta^4$ -quinone complexes that function as organometalloligands by binding to metal ions through the quinone oxygen atoms. The resulting supramolecular assemblies display a variety of interesting and potentially useful network topologies. An erratum to this article can be found at

Keywords:	Coordination networks hydrogen-bonding quinone complexes organometalloligand polymers self-assembly
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