| 在[Et3NH]Cl-XAlCl3离子液体催化下苯基二氯化磷的硫化 |
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| 引用本文： | 王忠卫,付强,王凤竹,王崇钢.在[Et3NH]Cl-XAlCl3离子液体催化下苯基二氯化磷的硫化[J].承德石油高等专科学校学报,2005,7(2):5-8. |
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| 作者姓名： | 王忠卫 付强 王凤竹 王崇钢 |
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| 作者单位： | 山东科技大学化工学院,山东,青岛,266510;中国航空油料总公司齐鲁代表处,山东,淄博,255434;山东石大胜华化工股份有限公司,山东,东营,257500 |
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| 摘 要： | 研究了苯基二氯化磷(DCPP)在含AlCl3的离子液体催化剂存在下,硫化合成苯基硫代膦酰氯(DCPPS)的反应特点.结果表明,离子液体(ILs)对反应有较好的催化活性,较传统催化方式表现出催化剂用量少、分离方式简便、原料和催化剂可回收等特点,克服了传统反应中产品难分离、污染重的缺点,为DCPPS的绿色合成提供了新的方法.
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| 关 键 词： | 苯基硫代膦酰氯 离子液体 绿色合成 |
| 文章编号： | 1008-9446(2005)02-0005-04 |
| 修稿时间： | 2005年1月19日 |
Green Synthesis of Dichlorophenylphosphine Sulfide Using Triethylhydrogenammonium Chloride-XAlCl3 Ionic Liquids as Catalyst |
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| WANG Zhong-wei,FU Qiang,WANG Feng-zhu,WANG Chong-gang.Green Synthesis of Dichlorophenylphosphine Sulfide Using Triethylhydrogenammonium Chloride-XAlCl3 Ionic Liquids as Catalyst[J].Journal of Chengde Petroleum College,2005,7(2):5-8. |
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| Authors: | WANG Zhong-wei FU Qiang WANG Feng-zhu WANG Chong-gang |
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| Abstract: | Triethylhydrogenammonium Chloride-XAlCl_3 ionic liquids(ILs) were used as catalyst in reactions for clean synthesis of dichlorophenylphosphine sulfide(DCPPS).One of the reactions was to catalyze the reaction of sulfur and dichlorophenylphosphine(DCPP) and the other reaction was to catalyze the one-pot reaction of benzene,phosphorus chloride and sulfur.A simple product isolation procedure was achieved,and the effects of the ILs composition,reaction time,and quantity of the ILs on the reactions were studied.The ILs showed reusable and low consumption characters in the reaction of sulfur and DCPP.Thus the Cl-XAlCl_3 ionic liquids gave this reaction a green character. |
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| Keywords: | dichlorophenyphosphine sulfide inoic liquids clean synthesis |
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