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Formic acid in caustic cephalic secretions of stingless bee,Oxytrigona (Hymenoptera: Apidae)
Authors:D. W. Roubik  B. H. Smith  R. G. Carlson
Affiliation:(1) Smithsonian Tropical Research Institute APDO, 2072 Balboa, Republic of Panama;(2) APO, 34002-0011 Miami, Florida;(3) Department of Entomology, University of Kansas, 66045 Lawrence, Kansas;(4) Department of Chemistry, University of Kansas, 66045 Lawrence, Kansas;(5) Present address: Dept. of Entomology, University of California at Berkeley, 94720 Berkeley, CA
Abstract:The cephalic extracts of two species in the stingless bee genusOxytrigona were analyzed. Extracts made in diethyl ether, and then derivatized with diphenyldiazomethane, revealed large quantities of formic acid, potentially a major defensive secretion of this stingless bee group. We additionally identify several hydrocarbons, aldehydes, ketones, and acetates. Novel diketones identified by others were detected in both species.
Keywords:Defensive secretions  formic acid  Oxytrigona  Hymenoptera  Apidae  stingless bees  mandibular glands  Meliponinae
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