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再生丝素蛋白/聚乙烯醇共混纳米纤维的静电纺丝研究
引用本文:刘芸,薛华育,戴礼兴. 再生丝素蛋白/聚乙烯醇共混纳米纤维的静电纺丝研究[J]. 合成纤维, 2006, 35(8): 13-16,19
作者姓名:刘芸  薛华育  戴礼兴
作者单位:苏州大学材料工程学院,江苏,苏州,215021;苏州大学材料工程学院,江苏,苏州,215021;苏州大学材料工程学院,江苏,苏州,215021
基金项目:国家973计划资助(编号2005CB623906),江苏省高校自然基金项目(编号04KJB430132)。
摘    要:以静电纺丝方法制备再生丝素蛋白/聚乙烯醇共混纳米纤维。研究了共混配比、溶液浓度、添加剂含量及电纺电压、喷丝距离等因素对纤维成形及纤维有关性能的影响。研究表明:与聚乙烯醇共混后再生丝素纤维的柔韧性有一定改善,适当增加PVA在共混物中的含量、提高纺丝液浓度以及纺丝电压有利于改善共混溶液的可纺性。另外,加入丙三醇虽可使纤维直径的均匀性有所提高,但却不利于纤维成形。

关 键 词:静电纺丝  丝素  聚乙烯醇  共混  纳米纤维
文章编号:1001-7054(2006)08-0013-04
收稿时间:2006-01-06
修稿时间:2006-01-06

Study on SF/PVA Blending Nanofibers by Electrospinning
LIU Yun,XUE Hua-yu,DAI Li-xing. Study on SF/PVA Blending Nanofibers by Electrospinning[J]. Synthetic Fiber in China, 2006, 35(8): 13-16,19
Authors:LIU Yun  XUE Hua-yu  DAI Li-xing
Affiliation:College of Polymer Science and Engineering, Soochow University, Jiangsu Suzhou 215021
Abstract:In this paper, silk fibroin and polyvinyl alcohol (SF/PVA) blend nanofibers were made by electrospinning and its dominating factors, such as blending ratio, concentration of spinning solution, additive, voltage, and distance between the capillary and collecting screen were studied. By blending with PVA, the rigidity and fragile properties of regenerated SF could be improved to some extent. With increasing the amount of PVA in the blend, concentration of spinning solution and the voltage of electrospinning, spinnability of the solution could be favored. Besides, the uniformity of the nanofibers could be increased by the addition of glycerin, but the coagulation effect of the nanofibers was decreased.
Keywords:electrospinning   SF   PVA   blend   nanofiber
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