Formation and corrosion properties of Fe-based bulk metallic glasses

Bulk metallic glass (BMG) formation was explored in the Fe-B-Si-Nb alloy system though combined use of the atomic cluster line approach and the minor alloying strategy. The basic ternary compositions in the Fe-B-Si system were determined by the intersection points of two cluster lines, namely, Fe-B cluster to Si and Fe-Si cluster to B. 3at%-4at% Nb was added to the quaternary Fe-B-Si-Nb alloy. The casting experiments revealed that good glass-forming ability (GFA) occurred at the (Fe73.4Si8.2B18.4)96Nb4 composition, and 3-mm diameter BMG samples were made. The glass transition temperature (Tg), crystallization temperature (Tx, and supercooled liquid region (△Tx=Tx-Tg) of this BMG were measured to be 866, 889, and 23 K, respectively. The BMG shows a high Vickers hardness of about Hv 1164, a Young's modulus of 180 GPa, and a good corrosion resistance in the solutions of 1 mol/L HCl and 3 wt% NaCl.