| 浸渍活性炭吸附剂与碘甲烷反应动力学研究 |
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| 引用本文： | 章小林,李新怀,李耀会,李伦,吕小婉,李小定,李金林.浸渍活性炭吸附剂与碘甲烷反应动力学研究[J].工业催化,2017,25(3):36-38. |
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| 作者姓名： | 章小林 李新怀 李耀会 李伦 吕小婉 李小定 李金林 |
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| 作者单位： | 1.华烁科技股份有限公司，湖北 武汉 430074；2.中南民族大学化学与材料学院 催化材料科学国家民委－教育部重点实验室，湖北 武汉 430074 |
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| 基金项目： | 催化材料科学国家民委－教育部重点实验室开放基金（CHCL06009）资助项目 |
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| 摘 要： | 通过一定的理论假设,推导出碘甲烷与浸渍活性炭吸附剂反应速率方程,通过实验测定碘甲烷与吸附剂化学反应的表观活化能和指前因子。结果表明,碘甲烷与吸附剂是快速化学反应,利用该速率方程可计算理论化学反应碘容,还可以预测吸附剂的使用寿命。
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| 关 键 词： | 催化动力学 碘甲烷 吸附剂 浸渍活性炭 动力学 活化能 |
Kinetics of the reaction between carbon impregnated adsorbent and iodomethane |
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| Zhang Xiaolin,Li Xinhuai,Li Yaohui,Li Lun,Lü Xiaowan,Li Xiaoding,Li Jinlin.Kinetics of the reaction between carbon impregnated adsorbent and iodomethane[J].Industrial Catalysis,2017,25(3):36-38. |
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| Authors: | Zhang Xiaolin Li Xinhuai Li Yaohui Li Lun Lü Xiaowan Li Xiaoding Li Jinlin |
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| Affiliation: | 1.Haiso Technology Co.,Ltd.,Wuhan 430074,Hubei,China; 2.Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education,College of Chemistry and Material Science,South Central University for Nationalities,Wuhan 430074,Hubei,China |
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| Abstract: | Based on certain theoretical assumptions,the kinetic equation between carbon impregnated adsorbent and iodomethane was derived.With this equation,the apparent activation energy and pre-exponential factor of the reaction were determined by experiments.The results showed that the reaction of iodomethane and carbon impregnated adsorbent was fast chemical reaction,and the theoretical iodide-capacity of iodomethane reacted could be calculated by the kinetic equation.The service life of the iodomethane adsorbent could be predicted. |
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| Keywords: | catalytic kinetics iodomethane adsorbent impregnated activated carbon kinetics activation energy |
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