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同阴离子双盐体系分离过程图解法综合
引用本文:陈侠,徐显朕,伍联营,胡仰栋. 同阴离子双盐体系分离过程图解法综合[J]. 化工学报, 2017, 68(4): 1452-1458. DOI: 10.11949/j.issn.0438-1157.20161095
作者姓名:陈侠  徐显朕  伍联营  胡仰栋
作者单位:中国海洋大学化学化工学院, 山东 青岛 266100
基金项目:国家自然科学基金项目(21376231)。
摘    要:氯化钾是我国化肥生产的重要原料,包含氯化钾的无机盐体系的分离过程综合研究具有重要理论意义和应用价值。以NaCl-KCl-H2O体系为例,提出了一种同阴离子双盐体系分离过程的综合方法。该方法是通过分析同阴离子双盐体系的固液平衡关系,在温度的影响和同离子效应的基础上建立的。其利用图解法直接从相图中寻找可行的分离工艺流程,设计过程简便易行。分别给出NaCl-KCl-H2O体系的两个和MgCl2-KCl-H2O体系的一个过程综合案例,并给出了相应的工艺流程。

关 键 词:分离  综合  图解法  相平衡  同离子效应  设计  
收稿时间:2016-08-04
修稿时间:2016-12-29

Separation process synthesis by illustration method for disalt system with the same anionic
CHEN Xia,XU Xianzhen,WU Lianying,HU Yangdong. Separation process synthesis by illustration method for disalt system with the same anionic[J]. Journal of Chemical Industry and Engineering(China), 2017, 68(4): 1452-1458. DOI: 10.11949/j.issn.0438-1157.20161095
Authors:CHEN Xia  XU Xianzhen  WU Lianying  HU Yangdong
Affiliation:Collage of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, Shandong, China
Abstract:KCl is the important raw material for fertilizer production in China. The separation process synthesis for the salt-water systems with KCl has important theoretical significance and practical application value. With the example of NaCl-KCl-H2O system, this study has presented a synthesis method for the separation process synthesis of the disalt system with the same anionic. Based on the temperature affect and common-ion effect, this method was built by analyzing the solid-liquid equilibrium. The illustration method were used to determine the separation process form the phase diagram, the design process was very simple and practical. Two synthesis case of NaCl-KCl-H2O system and one of MgCl2-KCl-H2O system were given in the paper, respectively, and the corresponding technological processes were also given.
Keywords:separation  synthesis  illustration method  phase equilibrium  common-ion effect  design  
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