Solvent annealing assisted self-assembly of hydrogen-bonded interpolymer complexes of AB block copolymer/C homopolymer in thin film |
| |
Authors: | Chao Wang Tingmei Wang Qihua Wang |
| |
Affiliation: | a State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, PR China b Graduate School, Chinese Academy of Sciences, Beijing 100039, PR China |
| |
Abstract: | A simple process of solvent annealing has been shown to produce ordered self-assembly structures of poly(styrene)-block-poly(4-vinylpyridine) (PS-b-P4VP)/poly(4,4′-oxydiphenylenepyromellitamic acid) (POAA) block copolymer/homopolymer blends in thin film, where POAA chains selectively interact with P4VP blocks by strong interpolymer hydrogen-bonding. By simply exposing the thin film to benzene/NMP (0.97/0.03, in volume) vapor mixture, ordered microphase-separated structures with PS spherical microdomains distributed within P4VP/POAA complexes matrix were obtained. The formation of the microphase-separated structures could be attributed to the substantial mobility of PS blocks and P4VP/POAA complexes and enhanced repulsion between them under the benzene/NMP mixture vapor. When the volume ratio of benzene to NMP increased to 0.98/0.02, the increasing benzene in the mixture vapor induced the adhesive collision of spherical microphase-separated structures to form long “pearl necklaces”. With increasing volume ratio of benzene to NMP to 0.99/0.01, an ordered “pearl necklace” array oriented parallel to the film surface formed. The self-assembly structures were studied by FTIR spectroscopy, atomic force microscopy (AFM), and transmission electron microscopy (TEM). Finally, possible mechanism of self-assembly and formation of microphase morphology was proposed. |
| |
Keywords: | Block copolymer/homopolymer Self-assembly Solvent annealing |
本文献已被 ScienceDirect 等数据库收录! |
|