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Effect of pH on the morphology and optical properties of modified ZnO particles by SDS via a precipitation method
Authors:N. Samaele  S. Suwanboon
Affiliation:a Department of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, 90112, Thailand
b Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, 90112, Thailand
Abstract:ZnO particles were synthesized directly from an aqueous solution of zinc acetate dihydrate in the presence of sodium dodecyl sulfate (SDS) and sodium hydroxide at 70 °C. The morphological changes were investigated in the range of pH 8-12. The hexagonal prism-like shape was formed at pH 8 and 10 by inhibition of growth along the c direction whereas the small rod-like shape was observed at pH 12. The estimated band gap and the room temperature photoluminescence intensity in a visible region are dependent upon the geometrical shape and size of the ZnO particles.
Keywords:Zinc oxide   Sodium dodecyl sulfate   Precipitation
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