Oxidation and halogenation of jojoba wax |
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Authors: | Arjeh B Galun Sarina Grinberg Arieh Kampf Eleonora Shaubi |
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Affiliation: | (1) Applied Research Institute, Ben-Gurion University of the Negev, P.O. Box 1025, 84110 Beer-Sheva, Israel |
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Abstract: | The oxidation with hydrogen peroxide and permanganate and the allylic bromination, chlorination and chloro-etherification
of the olefinic bonds of the liquid wax extracted from beans of jojoba (Simmondsia chinensis) were studied. Hydrolytic splitting of the wax into its carboxylic and alcoholic components competed with most reactions
carried out in aqueous systems. The use of a suitable phase-transfer catalyst enabled the oxidation of the double bonds to
carboxyls using permanganate in aqueous systems. Reaction of the wax with hydrogen peroxide in formic acid yielded formates,
which were then hydrolyzed to vicinal glycols. The diglycols obtained by hydrogen peroxide oxidation were benzoylated. Allylic
chlorination of jojoba wax with t-butyl hypochlorite in organic solvents was carried out. Conditions were found for the allylic
bromination of the wax, yielding mono-, di-, tetra-, or octabromo derivatives. |
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