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高压环境中聚合物玻璃化转变温度的测量方法
引用本文:叶树明,蒋凯,蒋春跃,潘勤敏. 高压环境中聚合物玻璃化转变温度的测量方法[J]. 高分子材料科学与工程, 2010, 0(2): 160-162
作者姓名:叶树明  蒋凯  蒋春跃  潘勤敏
作者单位:浙江大学生物医学工程与仪器科学学院;浙江工业大学化工与材料科学学院;Department;Chemical;Engineering;University;Waterloo;
基金项目:国家自然科学基金资助项目(40676059)
摘    要:对高压环境中聚合物玻璃化转变温度(Tg)测量方法的现状与进展进行了综述。在常压测量法基础上发展起来的高压测量方法主要有:高压差示扫描量热法(HP-DSC)、蠕变柔量法等;原位光学法则是新近发展起来的一种非接触式测量方法。随着超临界流体技术与应用的发展及仪器科学自身的不断进步与完善,必将涌现出更多先进的测量技术与方法。

关 键 词:玻璃化转变温度  测量法  仪器  超临界二氧化碳  聚合物

Measurements of Glass Transition Temperature of Polymers in Supercritical Carbon Dioxide
YE Shu-ming,JIANG Kai,JIANG Chun-yue,PAN Qin-min. Measurements of Glass Transition Temperature of Polymers in Supercritical Carbon Dioxide[J]. Polymer Materials Science & Engineering, 2010, 0(2): 160-162
Authors:YE Shu-ming  JIANG Kai  JIANG Chun-yue  PAN Qin-min
Affiliation:1. College of Biomedical Engineering and Instrument Science;Zhejiang University;Hangzhou 310027;China;2. College of Chemical Engineering and Materials Science;Zhejiang University of Technology;Hangzhou 310014;3. Department of Chemical Engineering;University of Waterloo;Waterloo;Ontario;Canada N2L 3G1
Abstract:The most advanced methods and techniques used for measuring the glassy transition temperatures of polymers in high pressure gases, such as supercritical carbon dioxide, were reviewed. The representative methods include the high pressure differential scanning calorimetry (DSC) method, the high pressure creep compliance measurement technique, and the in situ optical measurement method, etc. It can be anticipated that more advanced measurement techniques will come forth, along with the development and applicat...
Keywords:glass transition temperature  measurement  instrument  supercritical carbon dioxide  polymer  
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