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WO3对掺铒碲酸盐玻璃的光谱性质的影响
引用本文:刘丽莎,吕树臣,孙江亭. WO3对掺铒碲酸盐玻璃的光谱性质的影响[J]. 激光技术, 2010, 34(3): 377-380. DOI: 10.3969/j.issn.1001-3806.2010.03.026
作者姓名:刘丽莎  吕树臣  孙江亭
作者单位:1.哈尔滨师范大学 物理系 哈尔滨 150025
基金项目:黑龙江省自然科学基金 
摘    要:为了满足光通信技术发展对光放大器材料的带宽要求,采用固相法制备了掺铒碲钨酸盐玻璃,研究了其光谱性质和热稳定性。用Judd-Ofelt理论计算了光谱的强度参量,根据McCumber理论计算了受激发射截面,其最大受激发射截面为1.85×10-20cm2,荧光半峰全宽最大值为104nm;用差热法分析了玻璃的热稳定性,析晶温度和转变温度之差最大值为131℃。结果表明,掺铒碲钨酸盐玻璃是一种良好的宽带放大器材料。

关 键 词:材料   Er3+   碲钨酸盐玻璃   热稳定性
收稿时间:2009-05-27
修稿时间:2009-07-08

The spectroscopic properties and the thermal stability of erbium-doped bismuth glasses
LIU Li-sha,L Shu-chen,SUN Jiang-ting. The spectroscopic properties and the thermal stability of erbium-doped bismuth glasses[J]. Laser Technology, 2010, 34(3): 377-380. DOI: 10.3969/j.issn.1001-3806.2010.03.026
Authors:LIU Li-sha  L Shu-chen  SUN Jiang-ting
Affiliation:LIU Li-sha,L(U) Shu-chen,SUN Jiang-ting
Abstract:The Er3+ doped bismuth glasses 10Bi2O3-55TeO2-(25-x)GeO2-10Na2O-xWO3-1ErO2(x=0,5,10,15)have been prepared. Optical properties and thermal stability of the erbium-doped bismuth glasses have been discussed. The study found: with the WO3 content increasing, Ω2, Ω4 and Ω6 gradually increase.According to the McCumber theory to caculated emission cross section in 1.5μm stimulated in erbium-doped bismuth glasses, the maximum stimulated emission cross section for the 1.85×10-20cm2, The maximun FWHM of Er3 + :4I15/2→4I13/2 is 104 nm. With the WO3 content increasing, ΔT first increase and then decrease, ΔT maximum is 131 ℃ in bismuth glasses.
Keywords:Er3+
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