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Rheological characterization of unsaturated polyester resin sheet molding compound
Authors:R J Silva-Nieto  B C Fisher  A W Birley
Abstract:This paper presents a theoretical and experimental analysis of the rheological behavior of sheet molding compound (SMC). The work analyses the squeeze flow in a parallel plate plastometer of SMC discs which contain 25 percent of fiber glass by weight. This method of flow characterization gives a good insight into the basic rheological behavior of SMC for the compression molding process when producing flat parts. The theoretical analysis applies to thickened and matured SMC at room temperature. The analysis treats SMC as a viscoelastic material having an equation of state with viscous, elastic and yield elements. The time variation of compressive force when squeezing SMC discs between two parallel plates (one fixed and one mobile) has been derived from the equation of state. The values of the viscous, elastic and yield parameters were determined by using a least squares method of curve fitting to the experimental results. There are two aspects to the reported experimental work. One aspect is concerned with showing that the three element model for the equation of state provides a realistic mathematical basis for characterizing the rheological behavior of SMC at room temperature. The other shows how the parallel plate plastometer can be used to give data which characterize SMC flow behavior under conditions similar to those of the actual compression molding process.
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