| 四羧基酞菁锌键合MCM-41的合成及其对Li/SOCl_2电池催化活性的影响 |
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| 引用本文： | 薛科创,张维萍.四羧基酞菁锌键合MCM-41的合成及其对Li/SOCl_2电池催化活性的影响[J].应用化工,2014(10):1856-1859. |
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| 作者姓名： | 薛科创 张维萍 |
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| 作者单位： | 1. 陕西国防工业职业技术学院 化学工程学院,陕西 西安,710300
2. 西北大学 化学与材料科学学院 陕西物理无机化学重点实验室,陕西 西安,710069 |
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| 摘 要： | 以航空煤油为溶剂,合成了四羧基酞菁锌配合物,将其键合在MCM-41上,以模拟电池为研究对象,测定了MCM-41-NH-PcZn对Li/SOCl2催化活性。结果表明,MCM-41-NH-PcZn使放电电压从空白的3.018 V提高到3.126 V,放电时间从空白的643 s增加到803 s,具有良好的催化活性。
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| 关 键 词： | Li/SOCl2电池 四羧基酞菁锌 MCM-41 MCM-41-NH-PcZn |
Synthesis of covalently anchored tetracarboxylphthalocyanines zinc(II)onto MCM=41 and effect of catalytic activity for Li/SOCl2 battery |
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| XUE Ke-chuang,ZHANG Wei-ping.Synthesis of covalently anchored tetracarboxylphthalocyanines zinc(II)onto MCM=41 and effect of catalytic activity for Li/SOCl2 battery[J].Applied chemical industry,2014(10):1856-1859. |
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| Authors: | XUE Ke-chuang ZHANG Wei-ping |
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| Affiliation: | XUE Ke-chuang;ZHANG Wei-ping;School of Chemical Engineering,Shaanxi Institute of Technology;Shaanxi Key Laboratory of Physico-Inorganic Chemistry,College of Chemistry and Materials Science,Northwest University; |
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| Abstract: | Tetraearboxylphthaloeyanine zine（ II）was synthesized with aviation kerosene as a solvent eova-lently anehored these tetraearboxylphthaloeyanines zine（ II ）onto MCM-41 was sueeessful. The eatalytie aetivity was tested for Li/SOCl2 battery and shown that diseharge voltage inereased from 3. 018 V to 3. 126 V,diseharge time inereased from 643 s to 803 s. |
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| Keywords: | Li/SOCl2 battery tetraearboxylphthaloeyanine zine(II) MCM-41 MCM-41-NH-PeZn |
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