1000°C Phase Relations and Superconductivity in the (Nd-Ce-Cu)-O Ternary System |
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Authors: | Charles N. Pieczulewski Kelly S. Kirkpatrick Thomas O. Mason |
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Affiliation: | Department of Materials Science and Engineering and Materials Research Center, The Technological Institute, Northwestern University, Evanston, Illinois 60208 |
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Abstract: | The phase relations involving the 24 K n -type Nd2- x Ce x CuO4 superconductor were investigated at 1000°C in air. The terminal solid solubility was confirmed to be x = 0.2. This solid solution is the only ternary phase in the Nd2O3–CeO2–CuO diagram. A binary (1 − y )CeO2– y NdO1.5 solid solution exists out to y = 0.4. Phase diagrams for NdO1.5–CeO2–CuO (1000°C) and NdO1.5–CeO2 (900° to 1500°C) are presented. |
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Keywords: | superconductors phases composition phase diagrams solid solutions |
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