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Adsorption behavior of Eu(III) on partially Fe(III)- or Ti(IV)-coated silica
Authors:Hee-Jung Im  Kyoung Kyun Park  Euo Chang Jung
Affiliation:1.Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, 150 Deokjin-dong, Yuseong-gu, Daejeon, 305-353, Republic of Korea
Abstract:The adsorption behavior of Eu(III) onto silica surface, which was partially coated with Fe(III) or Ti(IV), was investigated to determine Fe(III) or Ti(IV) effects on the surface reaction of lanthanides on mineral surfaces in groundwater. Compared with a parallel uncoated silica, the Fe(III)-coated silica did not enhance the adsorption of Eu(III). However, enhanced adsorption of Eu(III) on the Ti(IV)-coated silica was observed by increasing the amount of Ti(IV) on the silica surface.
Keywords:partially coated silica   Ti(IV) coating effects   enhanced adsorption   surface complexation.
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