| 甲酸甲酯与三聚甲醛偶联合成乙醇酸甲酯研究 Ⅱ.过磷酸催化反应机理初探 |
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| 引用本文： | 李志锋,陈樑,陈云华,杞卫东,黄静,陈明胜. 甲酸甲酯与三聚甲醛偶联合成乙醇酸甲酯研究 Ⅱ.过磷酸催化反应机理初探[J]. 天然气化工, 2003, 28(6): 9-11 |
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| 作者姓名： | 李志锋 陈樑 陈云华 杞卫东 黄静 陈明胜 |
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| 作者单位： | 1. 昆明理工大学一碳化工研究中心,昆明,650224
2. 云南化工研究院,昆明,650041 |
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| 摘 要： | 结合以过磷酸为催化剂催化甲酸甲酯与三聚甲醛偶联合成乙醇酸甲酯的实验结果,通过对反应过程压力变化分析、CO理论分压的计算、乙醇酸甲酯及甲氧基乙酸甲酯总产率等的对比研究,初步提出了有关过磷酸催化的反应机理,合理解释了反应现象。
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| 关 键 词： | 乙醇酸甲酯 甲酸甲酯 三聚甲醛 过磷酸 反应机理 |
| 文章编号： | 1001-9219(2003)06-09-03 |
| 修稿时间： | 2003-03-20 |
Synthesis of Methyl Glycolate from Formaldehyde and Methyl Formate with Superphosphoric Acid as Catalyst Ⅱ.Deduction of reaction mechanism |
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| LI Zhi-feng,CHEN Liang,CHEN Yun-hua,QI Wei-dong,Huang Jing,Chen Ming-sheng. Synthesis of Methyl Glycolate from Formaldehyde and Methyl Formate with Superphosphoric Acid as Catalyst Ⅱ.Deduction of reaction mechanism[J]. Natural Gas Chemical Industry, 2003, 28(6): 9-11 |
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| Authors: | LI Zhi-feng CHEN Liang CHEN Yun-hua QI Wei-dong Huang Jing Chen Ming-sheng |
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| Affiliation: | LI Zhi-feng~1,CHEN Liang~1,CHEN Yun-hua~1,QI Wei-dong~2,Huang Jing~1,Chen Ming-sheng |
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| Abstract: | Based on the analysis of experimental results, a preliminary mechanism for title reaction was supposed and by it the phenomena of experiments can be explained reasonably. |
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| Keywords: | mehtyl glycotate methyl formate trioxane superphosphoric acid reaction mechanism |
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