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钛酸钾晶须增韧尼龙66及其断面分形研究
引用本文:吕家桢,窦强,冯新,陆小华.钛酸钾晶须增韧尼龙66及其断面分形研究[J].高分子材料科学与工程,2001,17(2):154-157.
作者姓名:吕家桢  窦强  冯新  陆小华
作者单位:1. 南京化工大学化学工程系,
2. Dept. Of Chemical Engineering, Nanjing University of Chemical Technology,
基金项目:江苏省自然科学基金!(BJ980 6 0 ),国家杰出青年科学基金!(2 992 5 6 16 )资助项目
摘    要:钛酸钾晶须用弹性体表面改性后实现了对尼龙66的有效增韧,改性剂 氧树脂用量为晶须的1.5%(质量)时,复合体系的冲击强度比纯尼66提高132%,同时弯曲,拉伸强度分别提高55%和48%,采用显微图像灰度法,对晶须增韧尼龙进行了基于断面小岛周长-面积关系的分形研究,考察了小岛选取对断面分维数测量结果的影响,研究表明,测得的分维数随选取小岛的面积阈值增加而增大,面积阈值达500η^2(η为侧量码尺)后,分维数趋于稳定,晶须增韧尼龙的力学强度与材料断面分维数之间的变化规律一致,对于从材断断裂机制与断面形貌进行了解释。

关 键 词:断面分形  小岛法  钛酸钾  晶段增韧  尼龙66
文章编号:1000-7555(2001)02-0154-04

FRACTAL RESEARCH OF FRACTURE SURFACES OF POTASSIUM TITANATE WHISKERS TOUGHENED NYLON 66
Lü Jia-zhen,DOU Qiang,FENG Xin,LU Xiao-hua.FRACTAL RESEARCH OF FRACTURE SURFACES OF POTASSIUM TITANATE WHISKERS TOUGHENED NYLON 66[J].Polymer Materials Science & Engineering,2001,17(2):154-157.
Authors:Lü Jia-zhen  DOU Qiang  FENG Xin  LU Xiao-hua
Abstract:Nylon 66 was effectively toughened with potassium titanate whiskers which were surface modified with an elastic epoxy resin. When the content of epoxy resin was of 1.5 mass% of whiskers, impact stre ngth of the composite increased 132% compared with neat nylon, while bending and tensile strengths increased 55% and 48% respectively. Image gray level method was adopted to carry out fractal research of fracture surfaces of the composites. Fractal dimensional calculations were based on perimeter-area relation. The influence of the sizes of measured slit islands on result fractal dime nsions was discussed. It was found that with the area threshold of measured slit islands increasing, calculated fractal dimension increases first and becames st able after area threshold reaches about 500η2(η was yardstick). The relationships between mechanical properties of the composites and fractal dimensions of fracture surfaces were further examined. There was good consistence between mechanical properties and fractal dimension, which was explained from the fracture mechanism of composites and fracture morphology.
Keywords:fractal  slit island method  potassium titanate  whiskers  toughening  nylon
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