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High strength and high modulus carbon fibers
Affiliation:1. School of Materials Science and Engineering, Georgia Institute of Technology, 801 Ferst Dr. NW, Atlanta, GA 30332, USA;2. L.A. Giannuzzi & Associates LLC, 12580 Walden Run Dr., Fort Myers, FL 33913, USA;3. Department of Aerospace Engineering, University of Illinois at Urbana Champaign, 104 S. Wright St, Urbana, IL 61801, USA;1. Instituto de Ciencia de Materiales de Madrid, ICMM-CSIC, Cantoblanco, 28049 Madrid, Spain;2. Department of Solid State Physics, University of ?ód?, Pomorska 149/153, 90236 ?ód?, Poland;1. National and Local Joint Engineering Laboratory of Advanced Road Materials, Shanxi Transportation Research Institute, Taiyuan 030006, China;2. National Engineering Laboratory for Carbon Fiber Technology, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;1. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72# Wenhua Road, Shenyang, 110016, China;2. National Key Laboratory of Advanced Functional Composite Materials, Aerospace Research Institute of Materials and Processing Technology, Beijing, 100076, China;3. Laboratory of Polymer Physics and Chemistry, Beijing National Laboratory of Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China;4. University of Chinese Academy of Sciences, Beijing, 100049, China;5. University of Science and Technology of China, Hefei, 230026, China;1. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China;2. University of the Chinese Academy of Sciences, Beijing, 100049, China;3. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, China;1. Carbon Composite Materials Research Center, Korea Institute of Science and Technology, 92 Chudong-ro Bongdong-eup, Wanju-gun, Jeonbuk 55324, Republic of Korea;2. Department of Carbon Materials and Fiber Engineering, Chonbuk National University, Jeonju, Jeonbuk, 54896, Republic of Korea;3. Department of Nano Material Engineering, Korea University of Science and Technology, 217 Gajeong-ro Yuseong-gu, Daejeon, 34113, Republic of Korea;1. ATMT Research Institute, Department of Textile Engineering, Amirkabir University of Technology, P.O. Box 15875-4413, Tehran, Iran;2. Polymer Consult Buchner GmbH, Hamburg, Germany
Abstract:Carbon fibers have been processed from gel spun polyacrylonitrile copolymer on a continuous carbonization line at Georgia Tech (GT) with a tensile strength in the range of 5.5–5.8 GPa, and tensile modulus in the range of 354–375 GPa. This combination of strength and modulus is the highest for any continuous fiber reported to date, and the gel spinning route provides a pathway for further improvements in strength and modulus for mass production of carbon fibers. At short gauge length, fiber tensile strength was as high as 12.1 GPa, which is the highest value ever reported for a PAN based carbon fiber. Structure analysis shows random flaws of about 2 nm size, which results in limiting tensile strength of higher than 20 GPa. Inter-planar turbostratic graphite shear modulus in high strength carbon fibers is 30 GPa, while in graphite the corresponding value is only 4 GPa.
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