| 探针分子3-乙基-十一烷的合成 |
| |
| 引用本文： | 国海峰,杨旭,任鹤.探针分子3-乙基-十一烷的合成[J].化工技术与开发,2011,40(11):18-22. |
| |
| 作者姓名： | 国海峰 杨旭 任鹤 |
| |
| 作者单位： | 1. 大庆化工研究中心,黑龙江 大庆,163714
2. 大庆石化公司化工一厂裂解车间,黑龙江 大庆,163714 |
| |
| 摘 要： | 针对SAPO- 11的一维十元环直孔道结构,设计了具有特殊分子结构的长链烷烃3-乙基-十一烷.3-乙基-十一烷与目前常用的长直链探针分子相比,具有能卡在SAPO- 11分子筛孔口的特点,因此可以作为特殊的长链探针分子,结合直链探针分子,对SAPO-11负载催化剂在长链正构烷烃异构化反应中的孔口催化机理进行研究.3-乙基...
|
| 关 键 词： | 探针分子 孔口催化 3-乙基-十一烷 |
Synthesis of Probe Molecule 3-Ethylicundecane |
| |
| GUO Hai-feng,YA NG Xu,REN He.Synthesis of Probe Molecule 3-Ethylicundecane[J].Technology & Development of Chemical Industry,2011,40(11):18-22. |
| |
| Authors: | GUO Hai-feng YA NG Xu REN He |
| |
| Affiliation: | GUO Hai-feng,YANG Xu,REN He(Daqing Chemical Research Center,Daqing 163714,China) |
| |
| Abstract: | In allusion to the molecular sieve of SAPO-11 with unidimensional 10-rings pore channel,3-ethylicundecane was selected as probe molecule for its special molecular structure.Compared to the common long straight-chain structure alkanes,3-ethylicundecane had the character of being locked near the pore of SAPO-11.Thus,it was appropriate to be the probe molecules to study the mechanism of pore mouth catalysis,used with common high alkanes,in the isomerization reaction of high n-alkanes on the catalysts loaded on... |
| |
| Keywords: | probe moleculars catalytic orifice 3-ethylicundecane |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
