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5-Br-PADAP及其金属螯合物作为光信息存储材料的研究
引用本文:尚永辉,李华,孙家娟,刘彬.5-Br-PADAP及其金属螯合物作为光信息存储材料的研究[J].信息记录材料,2008,9(6).
作者姓名:尚永辉  李华  孙家娟  刘彬
作者单位:1. 咸阳师范学院,化学系,咸阳,712000;西北大学,分析科学研究所,西安,710069
2. 西北大学,分析科学研究所,西安,710069
3. 咸阳师范学院,化学系,咸阳,712000
基金项目:西北大学研究生交叉学科资助项目,咸阳师范学院专项科研基金 
摘    要:本文合成了2-(5-溴-2-吡啶偶氮)-5-二乙氨基酚(5-Br-PADAP)的Zn,Co,Cu,Ni的4种金属螯合物,利用紫外可见光谱仪和差热-热重分析系统分别研究了5-Br-PADAP及其Zn,Co,Cu,Ni的金属螯合物在溶液态的光谱学性质和热力学性质,并进一步研究了5-Br-PADAP·Ni和5-Br-PADAP·Co薄膜态的透射光和反射光性质。研究发现5-Br-PADAP·Co,5-Br-PADAP·Ni可以作为良好的光信息存储介质材料。

关 键 词:偶氮染料  光信息存储  5-Br-PADAP

The Study of 2- (5-bromo-2-pyridyazo) -5-diethylaminophenol and its metal chelates as Optical Information Storage Materials
SHANG Yong-hui,LI Hua,SUN Jia-juan,LIU Bin.The Study of 2- (5-bromo-2-pyridyazo) -5-diethylaminophenol and its metal chelates as Optical Information Storage Materials[J].Information Recording Materials,2008,9(6).
Authors:SHANG Yong-hui  LI Hua  SUN Jia-juan  LIU Bin
Abstract:The Zn,Co,Cu,Ni metal chelates of the 2-(5-bromo-2-pyridyazo)-5-diethyl- aminophenol(5-Br-PADAP),were synthetized and UV absorption and themo-ravimimetry (TG)and differential scanning calorimetry(DSC)were used to investigate their optical proper- ties and thermal properties when spin coat them on a k9 glass.In addition their reflection and transmission properties were studied.It is found the 5-Br-PADAP·Ni and 5-Br-PADAP·Co are good optical information storage materials.
Keywords:5-Br-PADAP
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