Coprecipitated Ni‐Co Bimetallic Nanocatalysts for Methane Dry Reforming |
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Authors: | Fateme Mirzaei Mehran Rezaei Fereshsteh Meshkani |
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Affiliation: | 1. University of Kashan, Institute of Nanoscience and Nanotechnology, Kashan, Iran.;2. University of Kashan, Faculty of Engineering, Chemical Engineering Department, Catalyst and Advanced Materials Research Laboratory, Kashan, Iran. |
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Abstract: | Methane dry reforming was studied over nanostructure bimetallic Ni‐Co‐MgO catalysts. The catalysts were prepared by coprecipitation with different Ni‐Co contents and characterized by XRD, BET, N2 adsorption/desorption, temperature‐programmed reduction (TPR), SEM, and temperature‐programmed oxidation (TPO) techniques. XRD results let conclude that all samples contained MgO crystallite phases. With a higher Ni content the intensity of the diffraction peaks became stronger, indicating growth of the crystallite size of the prepared solid solutions. BET analysis demonstrated that a higher Ni‐Co content decreased the surface area. The optimal catalyst could be determined which had the highest activity and a good stability in dry reforming reaction. |
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Keywords: | Methane dry reforming Nanoparticles Ni‐Co catalysts |
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