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Coprecipitated Ni‐Co Bimetallic Nanocatalysts for Methane Dry Reforming
Authors:Fateme Mirzaei  Mehran Rezaei  Fereshsteh Meshkani
Affiliation:1. University of Kashan, Institute of Nanoscience and Nanotechnology, Kashan, Iran.;2. University of Kashan, Faculty of Engineering, Chemical Engineering Department, Catalyst and Advanced Materials Research Laboratory, Kashan, Iran.
Abstract:Methane dry reforming was studied over nanostructure bimetallic Ni‐Co‐MgO catalysts. The catalysts were prepared by coprecipitation with different Ni‐Co contents and characterized by XRD, BET, N2 adsorption/desorption, temperature‐programmed reduction (TPR), SEM, and temperature‐programmed oxidation (TPO) techniques. XRD results let conclude that all samples contained MgO crystallite phases. With a higher Ni content the intensity of the diffraction peaks became stronger, indicating growth of the crystallite size of the prepared solid solutions. BET analysis demonstrated that a higher Ni‐Co content decreased the surface area. The optimal catalyst could be determined which had the highest activity and a good stability in dry reforming reaction.
Keywords:Methane dry reforming  Nanoparticles  Ni‐Co catalysts
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