| 溶液自由基法高分子量聚丙烯腈的合成 |
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| 引用本文： | 周吉松,吕永根,王小华,杨常玲,刘云芸.溶液自由基法高分子量聚丙烯腈的合成[J].高分子材料科学与工程,2010(4):40-42,46. |
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| 作者姓名： | 周吉松 吕永根 王小华 杨常玲 刘云芸 |
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| 作者单位： | 纤维材料改性国家重点实验室;东华大学材料科学与工程学院;东华大学化学化工与生物工程学院; |
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| 基金项目： | 国家973资助项目(2006CB605300);;上海市科委项目(07DJ14002) |
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| 摘 要： | 采用以偶氮二异丁腈(AIBN)为引发剂,丙烯腈(AN)与丙烯酰胺(AM)在二甲亚砜(DMSO)溶剂中的自由基溶液共聚合,考察了单体浓度,单体配比,引发剂含量,反应温度和聚合时间等对共聚反应的影响。分别用称量法和乌氏黏度计测定了反应的转化率和聚合物的相对分子质量,用红外光谱对聚合物的结构进行了分析。研究结果表明,提高反应温度及引发剂含量,则转化率升高,分子量下降。单体浓度越高,分子量及转化率均可提高。这符合自由基聚合的一般规律。通过工艺优化,共聚物的转化率可达90%以上,黏均分子量约21万。
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| 关 键 词： | 丙烯腈 丙烯酰胺 高平均分子量 炭纤维 溶液共聚合 |
Solution Radical Controlled Polymerization of High Average Molecular Weight Polyacrylonitrile |
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| ZHOU Ji-song,LV Yong-gen,WANG Xiao-hua,YANG Chang-ling,LIU Yun-yun.Solution Radical Controlled Polymerization of High Average Molecular Weight Polyacrylonitrile[J].Polymer Materials Science & Engineering,2010(4):40-42,46. |
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| Authors: | ZHOU Ji-song LV Yong-gen WANG Xiao-hua YANG Chang-ling LIU Yun-yun |
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| Affiliation: | 1. State Key Laboratory for Modification of Chemical Fibers and Polymer Matericals;Collegeof Materical Science and Engineering;Donghua University;2. College of Chemistry;Chemical Engineering and Biotechnology;Shanghai 201620;China |
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| Abstract: | Free-radical solution copolymerization of acrylamide(AM) and acrylonitrile(AN) was carried out in dimethyl sulfoxide(DMSO) using azodiisobutyronitrile(AIBN) as initiator. The effect of monomer concentration,ratio of monomer,initiator content,reaction temperature and polymerization time on copolymerization was studied. The conversion rate of the polymerization and the relative molecular weight of the product were determined by weight method and Ubbelodhe viscosimeter. IR was used to characterize the structur... |
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| Keywords: | acrylonitrile acrylamide high average molecular weight carbon fiber solution copolymerization |
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