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Influence of imidazolium-based ionic liquids on the performance of polyaniline-CoFe2O4 nanocomposites
Authors:Chunjiang LengJianhong Wei  Zhengyou LiuJing Shi
Affiliation:Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072, China
Abstract:Using cobalt ferrite (CoFe2O4) nanoparticles of different content as nucleation sites, polyaniline-CoFe2O4 nanofiber composites were successfully synthesized at the interface of water and ionic liquid via in-situ polymerization. Structure and morphology were investigated by TGA, TEM, XRD, and FT-IR. The influence of ionic liquids on the structure, conductivity and magnetic property of polyaniline-CoFe2O4 nanocomposites were studied in detail. The results show that imidazolium-based ionic liquids BMIPF6 acts as an anchor agent during the nanofiber composites formation process. Introduction of ionic liquids obviously improves the conductivity but weakens the magnetization of polyaniline-CoFe2O4 nanocomposites in the same [CoFe2O4]/[An] ratio.
Keywords:Polymer   Nanocomposite   Chemical synthesis   Conductivity   Magnetization
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